Driving Decarbonization in Cement - Through Technology Innovation
Inspired by its vision for a sustainable cement industry, Linde is advancing combustion and carbon capture technologies to help reduce the climate impact of this hard-to-abate sector.
Cementing a Lower-carbon Future
Cement is everywhere - in our buildings, roads, bridges and dams - yet its production is responsible for around 7% of global carbon dioxide (CO2) emissions. Many cement producers are keen to decarbonize their operations.
There are two main sources of carbon emissions in cement production. The first is calcination, where the feedstock limestone decomposes into calcium oxide (CaO) and CO2 (to form clinker) in a cement kiln at temperatures of around 1,450°C (2,642°F). This reaction is essential to produce clinker, making this a hard-to-abate process. This shifts the decarbonization focus to capture rather than avoidance. The second source of carbon emissions is related to the combustion of fossil fuels to generate the high temperatures needed in the kiln. These emissions can be reduced by using green hydrogen as the combustion fuel. And there are other ways to mitigate combustion-related emissions.
Post-combustion capture (PCC), for instance, is an effective way to reduce the CO2 emitted by the cement kiln during the production of clinker. In other words, the CO2 is captured after the combustion process. The flue gas is treated to separate and purify the CO2 stream. This can be achieved by means of advanced technologies such as carbon absorption using amine solutions. Alternatively, adsorptive technologies can be combined with cryogenic technologies to shrink carbon footprints further at lower cost. The effectiveness of PCC methods can be enhanced by using oxygen-enriched air or pure oxygen instead of air for the combustion process. This oxyfuel process results in a higher flame temperature and more efficient fuel burning.
Additionally, the reduction in nitrogen content increases the concentration of CO2 in the flue gases, making it easier to capture and purify.
Extending along the wider CO2 value chain, the captured and treated gas can then be used as a feedstock for other industrial processes or stored in special reservoirs. This captured gas can also be a welcome new source of CO2 to help secure supplies for the merchant market.
Right Fit for All Sources and Concentrations
Here at Linde, we offer a broad suite of carbon capture and utilization (CCU) technologies giving you the flexibility, scalability and cost efficiency you need to address today's emissions reduction challenges in cement. The solution or combination best suited to your operations will depend on the CO2 concentration in your source, your overall CCU strategy, utility pricing in your region and your investment budget. Our experts would be delighted to advise on the right fit for your setup.
Suited to just about all carbon sources and concentrations, our portfolio scales from content levels of 3% and less to higher concentrations in connection with oxyfuel combustion, for instance. In addition, we build - and operate if preferred - air separation units (ASUs) to supply oxygen to cement kilns. Reflecting our commitment to a closed loop system, we have also developed recycling concepts with partners such as Carboclave and CarbonCure. Our dedicated CO2 supply and control solutions enable you to further reduce the carbon impact of your concrete operations by feeding the captured carbon back into the curing process.
Read on for some of the highlights of our decarbonization offering for the cement industry.
HISOLVTM Solvent-based Carbon Capture Solution
This post-combustion capture (PCC) approach is a mature, field-proven technology to capture CO2 from flue gas streams. The gas is removed from the flue gas through chemical scrubbing with an aqueous amine-based solvent. This advanced amine wash technology allows for CO2 capture rates in excess of 95% with CO2 purities of 99.9 vol% (dry). An all-in-one offering combines our strength and proven track record in the design and delivery of turnkey industrial plants with the high-performance gas treatment technologies delivered by our license partners. This gives you an optimal interplay spanning solvent, process design, equipment and plant integration. Amine wash solutions can be implemented downstream of existing assets without interfering with upstream processes. For new assets, we develop sophisticated plant integration concepts offering optimized total costs of ownership. HISOLV is a popular choice for flue gas streams with low CO2 concentrations and in regions where fossil-fired energy is relatively affordable.
HISORP® CC Adsorption-based Carbon Capture Solution
Unlike our advanced amine wash offering, our HISORP solution runs solely on electrical energy. In theory, this could be sourced exclusively from renewables, making a huge contribution to decarbonization and helping cement companies navigate fluctuating utility prices. This makes HISORP CC an attractive option in geographies with mature renewable energy infrastructures and for flue gas streams with higher CO2 concentrations.
HISORP CC combines pressure swing adsorption (PSA) with our cryogenic separation and compression technologies. It is suited to pre- and post-combustion carbon capture for a variety of sources, delivering capture rates in excess of 95%. It scales with ease, supports different CO₂ feed concentrations and export products (gaseous, liquid or supercritical form), and delivers dry CO2 at purity levels ranging from industrial to high-purity food grade. The HISORP toolbox approach means you can select and tailor the modularized process units to create the perfect fit for your size, scale, feed stream and capture rate requirements.
HITREATTM CO2 Treatment Solutions
The CO2 off-gas from cement kilns captured by our HISOLVTM advanced amine wash technology may require post-processing to make it suitable for downstream use. Our HITREAT CO2 processing units (CPUs) are the ideal way to achieve this.
HITREAT spans all steps in the processing chain - from compression and purification to dehydration and even liquefaction - making it ideal for onward transport by road, rail or ship. Our HITREAT offering is like a toolbox. In other words, we combine the steps you need to meet your CO2 specifications. This could include the removal of trace components such as sulfur- or nitrogen-containing compounds, water, hydrocarbons, heavy metals and air gases. This toolbox approach includes all delivery options - you get CO2 in the purity and phase you need, whether that be gaseous, supercritical or liquefied.
First Commercial Carbon Capture Project in German Cement Industry
Heidelberg Materials Leads the Way with Commercial-scale CC Plant for Cement
Customer Snapshot:
Feed source: Flue gas from cement kiln
CO2 purity: Food-grade CO2
Capacity: Around 70,000 tons of CO2 per year
Process: OASE® blue*, purification, liquefaction and storage
Highlights: First commercial plant of its kind for the German cement industry
* BASF SE technology
Note: For the implementation of this project, Heidelberg Materials and Linde applied for and were granted funding in the amount of almost €15 million under the Decarbonization of Industry funding program managed by the Competence Center for Climate Change Mitigation in Energy-Intensive Industries (KEI) on behalf of the German government.